Collapse to view only § 421.331 - Specialized definitions.

§ 421.330 - Applicability: Description of the primary zirconium and hafnium subcategory.

The provisions of this subpart are applicable to discharges resulting from the production of zirconium or hafnium at primary zirconium and hafnium facilities. There are two levels of BPT, BAT, NSPS, PSES and PSNS provisions for this subpart. Facilities which only produce zirconium or zirconium/nickel alloys by magnesium reduction of zirconium dioxide are exempt from regulations. All other facilities are subject to these regulations.

§ 421.331 - Specialized definitions.

For the purpose of this subpart the general definitions, abbreviations, and methods of analysis set forth in 40 CFR part 401 shall apply to this subpart.

§ 421.332 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available.

Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart shall achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable technology currently available:

(a) Sand drying wet air pollution control.

BPT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)0.2500.102 Cyanide (total)0.1650.068 Lead0.2390.114 Nickel1.0910.721 Ammonia (as N)75.71033.280 Total suspended solids23.29011.080 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(b) Sand chlorination off-gas wet air pollution control.

BPT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zironium dioxide and hafnium dioxide produced Chromium (total)19.1307.825 Cyanide (total)12.6105.216 Lead18.2608.694 Nickel83.46055.210 Ammonia (as N)5,795.0002,547.000 Total suspended solids1,782.000847.700 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(c) Sand chlorination area-vent wet air pollution control.

BPT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)3.7511.534 Cyanide (total)2.4721.023 Lead3.5801.705 Nickel16.37010.830 Ammonia (as N)1,136.000449.500 Total suspended solids349.500166.200 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(d) SiCl4 purification wet air pollution control.

BPT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)3.2991.350 Cyanide (total)2.1740.900 Lead3.1491.500 Nickel14.4009.522 Ammonia (as N)999.500439.400 Total suspended solids307.400146.200 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(e) Feed makeup wet air pollution control.

BPT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)2.5011.023 Cyanide (total)1.6480.682 Lead2.3871.137 Nickel10.9107.217 Ammonia (as N)757.500333.000 Total suspended solids233.000110.800 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(f) Iron extraction (MIBK) steam stripper bottoms.

BPT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)0.9870.404 Cyanide (total)0.6510.269 Lead0.9420.449 Nickel4.3082.850 Ammonia (as N)299.100131.500 Total suspended solids92.00043.760 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(g) Zirconium filtrate.

BPT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)17.0706.982 Cyanide (total)11.2504.655 Lead16.2907.758 Nickel74.48049.260 Ammonia (as N)5,171.0002,273.000 Total suspended solids1,590.000756.400 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(h) Hafnium filtrate.

BPT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)0.0000.000 Cyanide (total)0.0000.000 Lead0.0000.000 Nickel0.0000.000 Ammonia (as N)0.0000.000 Total suspended solids0.0000.000 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(i) Calcining caustic wet air pollution control.

BPT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)3.9591.619 Cyanide (total)2.6091.080 Lead3.7791.799 Nickel17.27011.430 Ammonia (as N)1,199.000527.200 Total suspended solids368.900175.400 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(j) Pure chlorination wet air pollution control.

BPT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium and hafnium produced Chromium (total)16.8606.897 Cyanide (total)11.1104.598 Lead16.0907.663 Nickel73.57048.660 Ammonia (as N)5,108.0002,245.000 Total suspended solids1,571.000747.200 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(k) Reduction area-vent wet air pollution control.

BPT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium and hafnium produced Chromium (total)1.6220.663 Cyanide (total)1.0690.442 Lead1.5480.737 Nickel7.0774.681 Ammonia (as N)491.300216.000 Total suspended solids151.10071.880 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(l) Magnesium recovery off-gas wet air pollution control.

BPT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium and hafnium produced Chromium (total)9.1233.732 Cyanide (total)6.0132.488 Lead8.7084.147 Nickel39.81026.330 Ammonia (as N)2,764.0001,215.000 Total suspended solids850.100404.300 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(m) Magnesium recovery area-vent wet air pollution control.

BPT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium and hafnium produced Chromium (total)5.0682.073 Cyanide (total)3.3401.382 Lead4.8382.304 Nickel22.11014.630 Ammonia (as N)1,535.000675.000 Total suspended solids472.200224.600 pH( 1)( 1)

1 Within the range of 7.5 to 10.0. .

(n) Zirconium chip crushing wet air pollution control.

BPT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium and hafnium produced Chromium (total)0.0000.000 Cyanide (total)0.0000.000 Lead0.0000.000 Nickel0.0000.000 Ammonia (as N)0.0000.000 Total suspended solids0.0000.000 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(o) Acid leachate from zirconium metal production.

BPT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of pure zirconium produced Chromium (total)12.9705.304 Cyanide (total-8.5453.536 Lead12.3805.893 Nickel56.57037.420 Ammonia (as N)3,928.0001,727.000 Total suspended solids1,208.000574.600 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(p) Acid leachate from zirconium alloy production.

BPT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium contained in alloys produced Chromium (total)6.9392.839 Cyanide (total)4.5741.893 Lead6.6243.154 Nickel30.28020.030 Ammonia (as N)2,102.000924.200 Total suspended solids646.600307.600 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(q) Leaching rinse water from zirconium metal production.

BPT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium produced Chromium (total)25.93010.610 Cyanide (total)17.0907.072 Lead24.75011.790 Nickel113.20074.840 Ammonia (as N)7,856.0003,453.000 Total suspended solids2,416.0001,149.000 pH( 1)( 1)

1 Within the range of 7.5 to 10.0.

(r) Leaching rinse water from zirconium alloy production.

BPT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium in alloys produced Chromium (total)0.3470.142 Cyanide (total)0.2290.095 Lead0.3310.158 Nickel1.5151.002 Ammonia (as N)105.20046.240 Total suspended solids32.35015.390 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

§ 421.333 - Effluent limitations guidelines representing the degree of effluent reduction attainable by the application of the best available technology economically achievable.

Except as provided in 40 CFR 125.30 through 125.32, any existing point source subject to this subpart shall achieve the following effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable:

(a) Sand drying wet air pollution control.

BAT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)0.2100.085 Cyanide (total)0.1140.045 Lead0.1590.074 Nickel0.3120.210 Ammonia (as N)75.71033.280

(b) Sand chlorination off-gas wet air pollution control.

BAT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)16.0806.521 Cyanide (total)8.6943.478 Lead12.1705.651 Nickel23.91016.080 Ammonia (as N)5,795.0002,547.000

(c) Sand chlorination area-vent wet air pollution control.

BAT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)3.1541.279 Cyanide (total)1.7050.682 Lead2.3871.108 Nickel4.6883.154 Ammonia (as N)1,136.000499.500

(d) SiCl4 purification wet air pollution control.

BAT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)2.7741.125 Cyanide (total)1.5000.600 Lead2.0990.975 Nickel4.1242.774 Ammonia (as N)999.500439.400

(e) Feed makeup wet air pollution control.

BAT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)2.1030.852 Cyanide (total)1.1370.455 Lead1.5910.739 Nickel3.1262.103 Ammonia (as N)757.500333.000

(f) Iron extraction (MIBK) steam stripper bottoms.

BAT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)0.8300.337 Cyanide (total)0.4490.180 Lead0.6280.292 Nickel1.2340.830 Ammonia (as N)299.100131.500

(g) Zirconium filtrate.

BAT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)14.3505.819 Cyanide (total)7.7583.103 Lead10.8605.043 Nickel21.33014.350 Ammonia (as N)5,171.0002,273.00

(h) Hafnium filtrate.

BAT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)0.0000.000 Cyanide (total)0.0000.000 Lead0.0000.000 Nickel0.0000.000 Ammonia (as N)0.0000.000

(i) Calcining caustic wet air pollution control.

BAT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)3.3291.350 Cyanide (total)1.7990.720 Lead2.5191.170 Nickel4.9483.329 Ammonia (as N)1,199.000527.200

(j) Pure chlorination wet air pollution control.

BAT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium and hafnium produced Chromium (total)14.1805.748 Cyanide (total)7.6633.065 Lead10.7304.981 Nickel21.07014.180 Ammonia (as N)5,108.0002,245.000

(k) Reduction area-vent wet air pollution control.

BAT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium and hafnium produced Chromium (total)1.3640.553 Cyanide (total)0.7370.295 Lead1.0320.479 Nickel2.0271.364 Ammonia (as N)491.300216.000

(l) Magnesium recovery off-gas wet air pollution control.

BAT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium and hafnium produced Chromium (total)7.6713.110 Cyanide (total)4.1471.659 Lead5.8052.695 Nickel11.4007.671 Ammonia (as N)2,764.0001,215.000

(m) Magnesium recovery area-vent wet air pollution control.

BAT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium and hafnium produced Chromium (total)4.2621.728 Cyanide (total)2.3040.921 Lead3.2251.497 Nickel6.3354.262 Ammonia (as N)1,535.000675.000

(n) Zirconium chip crushing wet air pollution control.

BAT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium and hafnium produced Chromium (total)0.0000.000 Cyanide (total)0.0000.000 Lead0.0000.000 Nickel0.0000.000 Ammonia (as N)0.0000.000

(o) Acid leachate from zirconium metal production.

BAT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of pure zirconium produced Chromium (total)10.9004.420 Cyanide (total)5.8932.357 Lead8.2503.831 Nickel16.21010.900 Ammonia (as N)3,928.0001,674.000

(p) Acid leachate from zirconium alloy production.

BAT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium contained in alloys produced Chromium (total)5.8352.366 Cyanide (total)3.1541.262 Lead4.4162.050 Nickel8.6745.835 Ammonia (as N)2,102.000895.000

(q) Leaching rinse water from zirconium metal production.

BAT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of pure zirconium produced Chromium (total)21.8108.840 Cyanide (total)11.7904.715 Lead16.5007.661 Nickel32.41021.810 Ammonia (as N)7,856.0003,453.000

(r) Leaching rinse water from zirconium alloy production.

BAT Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium contained in alloys produced Chromium (total)0.2920.118 Cyanide (total)0.1580.063 Lead0.2210.103 Nickel0.4340.292 Ammonia (as N)105.20046.240

§ 421.334 - Standards of performance for new sources.

Any new source subject to this subpart shall achieve the following new source performance standards:

(a) Sand drying wet air pollution control.

NSPS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)0.2100.085 Cyanide (total)0.1140.045 Lead0.1590.074 Nickel0.3120.210 Ammonia (as N)75.71033.280 Total suspended solids8.5206.816 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(b) Sand chlorination off-gas wet air pollution control.

NSPS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)16.0806.521 Cyanide (total)8.6943.478 Lead12.1705.651 Nickel23.91016.080 Ammonia (as N)5,795.0002,547.000 Total suspended solids652.100521.000 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(c) Sand chlorination area-vent wet air pollution control.

NSPS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)3.1541.279 Cyanide (total)1.7050.682 Lead2.3871.108 Nickel4.6883.154 Ammonia (as N)1,136.000499.500 Total suspended solids127.900102.300 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(d) SiC14 purification wet air pollution control.

NSPS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)2.7741.125 Cyanide (total)1.5000.600 Lead2.0990.975 Nickel4.1242.774 Ammonia (as N)999.500439.400 Total suspended solids112.50089.980 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(e) Feed makeup wet air pollution control.

NSPS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)2.1030.852 Cyanide (total)1.1370.455 Lead1.5910.739 Nickel3.1262.103 Ammonia (as N)757.500333.000 Total suspended solids85.25068.200 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(f) Iron extraction (MIBK) steam stripper bottoms.

NSPS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)0.8300.337 Cyanide (total)0.4490.180 Lead0.6280.292 Nickel1.2340.830 Ammonia (as N)299.100131.500 Total suspended solids33.66026.930 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(g) Zirconium filtrate.

NSPS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)14.3505.819 Cyanide (total)7.7583.103 Lead10.8605.043 Nickel21.33014.350 Ammonia (as N)5,171.0002,273.000 Total suspended solids581.900465.500 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(h) Hafnium filtrate.

NSPS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)0.0000.000 Cyanide (total)0.0000.000 Lead0.0000.000 Nickel0.0000.000 Ammonia (as N)0.0000.000 Total suspended solids0.0000.000 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(i) Calcining caustic wet air pollution control.

NSPS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)3.3291.350 Cyanide (total)1.7990.720 Lead2.5191.170 Nickel4.9483.329 Ammonia (as N)1,199.000527.200 Total suspended solids135.000108.000 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(j) Pure chlorination wet air pollution control.

NSPS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium and hafnium produced Chromium (total)14.1805.748 Cyanide (total)7.6633.065 Lead10.7304.981 Nickel21.07014.180 Ammonia (as N)5,108.0002,245.000 Total suspended solids574.800459.800 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(k) Reduction area-vent wet air pollution control.

NSPS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium and hafnium produced Chromium (total)1.3640.553 Cyanide (total)0.7370.295 Lead1.0320.479 Nickel2.0271.364 Ammonia (as N)491.300216.000 Total suspended solids55.29044.230 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(l) Magnesium recovery off-gas wet air pollution control.

NSPS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium and hafnium produced Chromium (total)7.6713.110 Cyanide (total)4.1471.659 Lead5.8052.695 Nickel11.4007.671 Ammonia (as N)2,764.0001,215.000 Total suspended solids404.300248.800 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(m) Magnesium recovery area-vent wet air pollution control.

NSPS Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium and hafnium produced Chromium (total)4.2621.728 Cyanide (total)2.3040.921 Lead3.2251.497 Nickel6.3354.262 Ammonia (as N)1,535.000675.000 Total suspended solids172.800138.200 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(n) Zirconium chip crushing west air pollution control.

NSPS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium and hafnium produced Chromium (total)0.0000.000 Cyanide (total)0.0000.000 Lead0.0000.000 Nickel0.0000.000 Ammonia (as N)0.0000.000 Total suspended solids0.0000.000 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(o) Acid leachate from zirconium metal production.

NSPS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of pure zirconium produced Chromium (total)10.9004.420 Cyanide (total)5.8932.357 Lead8.2503.831 Nickel16.21010.900 Ammonia (as N)3,928.0001,674.000 Total suspended solids442.000353.600 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(p) Acid leachate from zirconium alloy production.

NSPS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium contained in alloys produced Chromium (total)5.8352.366 Cyanide (total)3.1541.262 Lead4.4162.050 Nickel8.6745.835 Ammonia (as N)2,102.000895.800 Total suspended solids236.600189.300 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(q) Leaching rinse water from zirconium metal production.

NSPS Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of pure zirconium produced Chromium (total)21.8108.840 Cyanide (total)11.7904.715 Lead16.5007.661 Nickel32.41021.810 Ammonia (as N)7,856.0003,453.000 Total suspended solids884.000707.200 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

(r) Leaching rinse water from zirconium alloy production.

NSPS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium contained in alloys produced Chromium (total)0.2920.118 Cyanide (total)0.1580.063 Lead0.2210.103 Nickel0.4340.292 Ammonia (as N)105.20046.240 Total suspended solids11.8409.468 pH( 1)( 1)

1 Within the range of 7.5 to 10.0 at all times.

§ 421.335 - [Reserved]

§ 421.336 - Pretreatment standards for new sources.

Except as provided in 40 CFR 403.7, any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve the following pretreatment standards for new sources. The mass of wastewater pollutants in primary zirconium and hafnium process wastewater introduced into a POTW shall not exceed the following values:

(a) Sand drying wet air pollution control.

PSNS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)0.2100.085 Cyanide (total)0.1140.045 Lead0.1590.074 Nickel0.3120.210 Ammonia (as N)75.71033.280

(b) Sand chlorination off-gas wet air pollution control.

PSNS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)16.0806.521 Cyanide (total)8.6903.478 Lead12.1705.651 Nickel23.91016.080 Ammonia (as N)5,795.0002,547.000

(c) Sand chlorination area vent wet air pollution control.

PSNS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)3.1541.279 Cyanide (total)1.7050.682 Lead2.3871.108 Nickel4.6883.154 Ammonia (as N)1,136.000499.500

(d) SiCl4 purification wet air pollution control.

PSNS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)2.7741.125 Cyanide (total)1.5000.600 Lead2.0990.975 Nickel4.1242.774 Ammonia (as N)999.500439.400

(e) Feed makeup wet air pollution control.

PSNS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)2.1030.852 Cyanide (total)1.1370.455 Lead1.5910.739 Nickel3.1262.103 Ammonia (as N)757.500333.000

(f) Iron extraction (MIBK) steam stripper bottoms.

PSNS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)0.8300.337 Cyanide (total)0.4490.180 Lead0.6280.292 Nickel1.2340.830 Ammonia (as N)299.100131.500

(g) Zirconium filtrate.

PSNS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)14.3505.819 Cyanide (total)7.7583.103 Lead10.8605.043 Nickel21.34014.350 Ammonia (as N)5,171.0002,273.000

(h) Hafnium filtrate.

PSNS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)0.0000.000 Cyanide (total)0.0000.000 Lead0.0000.000 Nickel0.0000.000 Ammonia (as N)0.0000.000

(i) Calcining caustic wet air pollution control.

PSNS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium dioxide and hafnium dioxide produced Chromium (total)3.3291.350 Cyanide (total)1.7990.720 Lead2.5191.170 Nickel4.9483.329 Ammonia (as N)1,199.000527.200

(j) Pure chlorination wet air pollution control.

PSNS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium and hafnium produced Chromium (total)14.1805.748 Cyanide (total)7.6633.065 Lead10.7304.981 Nickel21.00714.180 Ammonia (as N)5,108.0002,245,000

(k) Reduction area-vent wet air pollution control.

PSNS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of Zirconium and hafnium produced Chromium (total)1.3640.553 Cyanide (total)0.7370.295 Lead1.0320.479 Nickel2.0271.364 Ammonia (as N)491.300216.000

(l) Magnesium recovery off-gas wet air pollution control.

PSNS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium and hafnium produced Chromium (total)7.6713.110 Cyanide (total)4.1471.659 Lead5.8052.695 Nickel11.4007.671 Ammonia (as N)2,764.0001,215.000

(m) Magnesium recovery area-vent wet air pollution control.

PSNS Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium and hafnium produced Chromium (total)4.2621.728 Cyanide (total)2.3040.921 Lead3.2251.497 Nickel6.3354.262 Ammonia (as N)1,535,000675.00

(n) Zirconium chip crushing wet air pollution control.

PSNS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium and hafnium produced Chromium (total)0.0000.000 Cyanide (total)0.0000.000 Lead0.0000.000 Nickel0.0000.000 Ammonia (as N)0.0000.000

(o) Acid leachate from zirconium metal production.

PSNS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of pure zirconium produced Chromium (total)10.9004.420 Cyanide (total)5.8932.357 Lead8.2503.831 Nickel16.21010.900 Ammonia (as N)3,928.0001,674.00

(p) Acid leachate from zirconium alloy production.

PSNS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium contained in alloys produced Chromium (total)5.8352.366 Cyanide (total)3.1541.262 Lead4.4162.050 Nickel8.6745.835 Ammonia (as N)2,102.000895.800

(q) Leaching rinse water from zirconium metal production.

PSNS Limitations for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of pure zirconium produced Chromium (total)21.8108.840 Cyanide (total)11.7904.715 Lead16.5007.661 Nickel32.41021.810 Ammonia (as N)7,856.0003,453.000

(r) Leaching rinse water from zirconium alloy production.

PSNS for the Primary Zirconium and Hafnium Subcategory

Pollutant or pollutant property Maximum for any 1 day Maximum for monthly average mg/kg (pounds per million pounds) of zirconium contained in alloys produced Chromium (total)0.2920.118 Cyanide (total)0.1580.063 Lead0.2210.103 Nickel0.4340.292 Ammonia (as N)105.20046.240

§ 421.337 - [Reserved]